Mathematical Modeling of the Selective Transport of Singly Charged Ions Through Multilayer Composite Ion-Exchange Membrane during Electrodialysis

نویسندگان

چکیده

Abstract The deposition of several alternating anion- and cation-exchange surface layers (layer-by-layer method) is a promising technique for the modification ion-exchange membranes, which makes it possible to essentially increase their selectivity singly charged ions. This paper presents one-dimensional model, based on Nernst–Planck–Poisson equations describes competitive transfer doubly ions through multilayer composite membrane. It has been revealed first time that, as in earlier studied case bilayer membrane, dependence specific permselectivity coefficient ( P 1/2 ) membrane electrical current density passes maximum $$\left( {P_{{{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-0em} 2}}}^{{\max }}} \right).$$ shown that an number nanosized bilayers n leads growth $$P_{{{1 }},$$ but flux preferably transferred ion decreases this case. established }}$$ attained at underlimiting densities relatively low potential drop. simulated dependences qualitatively agree with known literature experimental theoretical results.

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ژورنال

عنوان ژورنال: Membranes and membrane technologies

سال: 2022

ISSN: ['2517-7516', '2517-7524']

DOI: https://doi.org/10.1134/s251775162206004x