Mathematical Modeling of the Selective Transport of Singly Charged Ions Through Multilayer Composite Ion-Exchange Membrane during Electrodialysis
نویسندگان
چکیده
Abstract The deposition of several alternating anion- and cation-exchange surface layers (layer-by-layer method) is a promising technique for the modification ion-exchange membranes, which makes it possible to essentially increase their selectivity singly charged ions. This paper presents one-dimensional model, based on Nernst–Planck–Poisson equations describes competitive transfer doubly ions through multilayer composite membrane. It has been revealed first time that, as in earlier studied case bilayer membrane, dependence specific permselectivity coefficient ( P 1/2 ) membrane electrical current density passes maximum $$\left( {P_{{{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-0em} 2}}}^{{\max }}} \right).$$ shown that an number nanosized bilayers n leads growth $$P_{{{1 }},$$ but flux preferably transferred ion decreases this case. established }}$$ attained at underlimiting densities relatively low potential drop. simulated dependences qualitatively agree with known literature experimental theoretical results.
منابع مشابه
Gas Permeation Modeling through a Multilayer Hollow Fiber Composite Membrane
In this study, a time-dependent 2D axisymmetric model of a multilayer hollow fiber composite membrane for gas separation is proposed. In spite of the common multilayer membranes, which a dense layer coated on a porous support layer and subjected into the feed stream, here, the porous support is exposed to the feed gas. In this regard, the governing equations of species transport are developed f...
متن کاملSelective Transport of Propylene by Silver Ion Complex Through an Immobilized Liquid Membrane
متن کامل
Simulation study of the transport properties of ions through ion channels serving as primary components of a nanobiosensor
Ion channels are naturally occurring pores through the proteins that regulate the passage of ions and thus maintain the concentration of ions inside and outside the cell. The ion channels control many physiological functions and they can show selectivity for a specific ion. Ion channels are mostly observed in nerve cells and muscle cells. The influx of ions into cells can be regulated by a gate...
متن کاملSelective and Efficient Ligandless Water-in-Oil Emulsion Liquid Membrane Transport of Thorium(IV) Ions
The present paper concerns on the selective and very efficient transport of thorium(IV) ions from aqueous solutions through an emulsion liquid membranes composed by paraffin and a surfactant, without carrier requirement. The influence of pH of the external aqueous phase, the surfactant concentration in the membrane phase, the type, and concentration of th...
متن کاملElectrodialysis of Blood Using Ion-Exchange Membranes
THE correction of electrolyte imbalance and the removal of retention products of the blood during renal failure is at present achieved by the use of artificial kidneys which permit the diffusion of solutes through a semi-permeable membrane. Several types of apparatus used successfully for hemodialysis include those described by Kolff and Watschinger (1956) and Alwall, Norviit, and Steins (1948)...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Membranes and membrane technologies
سال: 2022
ISSN: ['2517-7516', '2517-7524']
DOI: https://doi.org/10.1134/s251775162206004x